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    Please use this identifier to cite or link to this item: http://asiair.asia.edu.tw/ir/handle/310904400/17290

    Title: Modeling liquid thermal explosion reactor containing tert-butyl peroxybenzoate
    Authors: 林駿憑;Lin, Chun-Ping
    Contributors: 保健營養生技學系
    Keywords: Differential scanning calorimetry (DSC);Green thermal analysis technology;Liquid thermal explosion;Tert-butyl peroxybenzoate;Thermal explosion hazard
    Date: 2010-10
    Issue Date: 2012-11-26 10:31:06 (UTC+8)
    Abstract: This study investigated the role played by green thermal analysis technology in promoting the use of resources, preventing pollution, reducing energy consumption and protecting the environment. The chemical tert-butyl peroxybenzoate (TBPB) has been widely employed in the petrifaction industries as an initiator of polymerization formation agent. This study established the thermokinetic parameters and thermal explosion hazard for a reactor containing TBPB via differential scanning calorimetry (DSC). To simulate thermokinetic parameters, a 5-ton barrel reactor of liquid thermal explosion model was created in this study. The approach was to develop a precise and effective procedure on thermal decomposition, runaway, and thermal hazard properties, such as activation energy (E a), control temperature (CT), critical temperature (TCR), emergency temperature (ET), heat of decomposition (∆H d), self-accelerating decomposition temperature (SADT), time to conversion limit (TCL), total energy release (TER), time to maximum rate under isothermal condition (TMR iso), etc. for a reactor containing TBPB. Experimental results established the features of thermal decomposition and huge size explosion hazard of TBPB that could be executed as a reduction of energy potential and storage conditions in view of loss prevention.
    Appears in Collections:[食品營養與保健生技學系] 期刊論文

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