ASIA unversity:Item 310904400/17344
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    题名: Preparation of Hydroquinone-Containing Polymers by ROMP.
    作者: 楊雅甄;Yang, Ya-Chen
    贡献者: 保健營養生技學系
    关键词: ROMP;Poly mer iza tion;Benzonorbornadiene;Hydroquinone.
    日期: 2001
    上传时间: 2012-11-26 10:31:47 (UTC+8)
    摘要: "Poly mers con tain ing hydroquinone moi eties are of cur -
    rent in ter est due to their spe cial re dox prop er ties. These prop -
    er ties might lead to ap pli ca tions such as charge stor age ma te -
    rial in or ganic sec ond ary bat ter ies1
    as well as charge in jec tion
    lay ers in electroluminscence de vices.2
    Ring open ing me tath -
    e sis poly mer iza tion3
    (ROMP) of quinone and hydroquinone-
    fused norbornadiene de riv a tives 1-4 pro vided an ef fi cient
    way for the prep a ra tion of such type of mol e cules. A pre vi ous
    re port on the prep a ra tion of 7 used a bisketal de riv a tive of 3
    as start ing mono mer,4
    since ROMP di rectly from 3 does not
    pro ceed suc cess fully. Our find ings in di cated that both 1a and
    1b could be uti lized as good start ing ma te ri als for the syn the -
    ses of 5a and 5b. A sim i lar re ac tion for 2a also pro ceeded
    well for the prep a ra tion of the cor re spond ing poly mer 6a"
    显示于类别:[食品營養與保健生技學系] 期刊論文


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