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    Please use this identifier to cite or link to this item: http://asiair.asia.edu.tw/ir/handle/310904400/2233


    Title: Preparation and Reduction of Hexahydro[2.2]paracyclophane
    Authors: Ya-Chen Yang;Shaw-Tao Lin
    Contributors: 保健營養生技學系
    Date: 1997
    Issue Date: 2009-11-02 09:53:06 (UTC+8)
    Abstract: Hexahydro[2.2]paracyclophane (6) and related compounds were prepared from the extrusion of sulfur dioxide from 2,11-dithia-4,5,6,7,8,9-hexahydro[3.3]paracyclophane 2,2,11,11-tetraoxide (9) by either the Ramberg−Backlund reaction or a flash pyrolysis. Compound 6 is the first cyclophane to contain both a benzene ring and a cyclohexane ring. Birch reduction of compound 6 gave a diene containing two double bonds in the same ring, which is different from the dienes obtained from the catalytic hydrogenation of [2.2]paracyclophane.
    Relation: Journal of Organic Chemistry, 62(9):2727–2731
    Appears in Collections:[食品營養與保健生技學系] 期刊論文

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